Comment 7 for bug 366630

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Nicolò Chieffo (yelo3) wrote : Re: [Bug 366630] Re: gnome-sound-properties no default mixer track selected

No, my issue is that the default mixer is the pulseaudio _capture_
device, instead of the alsa mixer.

It selects the alsa mixer only because "Master" is not selected.
If for an error you click on "Master" without changing to "alsa" or
"playback" the volume keys won't work.