I am experiencing this same issue on Ubuntu 14.04 with xubuntu-desktop installed.
To summarize:
* I set a new keybinding in Settings -> Window Manager. In my case it was "Alt-F1" to switch to workspace 1.
* When I log out or reboot the key binding is lost and "Alt-F1" does nothing. Settings -> Window Manager still says it's bound to "Alt-F1" but it does not function.
* If I re-set the key by double-clicking "Alt-F1" and then pressing "Alt-F1" again it works.
* In the file `~/.config/xfce4/xfconf/xfce-perchannel-xml/xfce4-keyboard-shortcuts.xml` multiple definitions exist for the same key combination and also for `workspace_1_key`.
I have tried the following fixes:
* In Settings -> Window Manager "clear" the key first. It shows "Ctrl-F1" (the old value) on the first click and then shows "" - the value I would expect on the second click. I then re-bind the "Alt-F1" key.
* In Settings -> Settings Manager -> Settings Editor -> xfce4-keyboard-shortcuts I have tried un-clicking and re-clicking "override" two times in a row.
I will report back as to whether these fixes work or not. Obviously this should be fixed in the code though.
I am experiencing this same issue on Ubuntu 14.04 with xubuntu-desktop installed.
To summarize:
* I set a new keybinding in Settings -> Window Manager. In my case it was "Alt-F1" to switch to workspace 1. xfce4/xfconf/ xfce-perchannel -xml/xfce4- keyboard- shortcuts. xml` multiple definitions exist for the same key combination and also for `workspace_1_key`.
* When I log out or reboot the key binding is lost and "Alt-F1" does nothing. Settings -> Window Manager still says it's bound to "Alt-F1" but it does not function.
* If I re-set the key by double-clicking "Alt-F1" and then pressing "Alt-F1" again it works.
* In the file `~/.config/
I have tried the following fixes:
* In Settings -> Window Manager "clear" the key first. It shows "Ctrl-F1" (the old value) on the first click and then shows "" - the value I would expect on the second click. I then re-bind the "Alt-F1" key. shortcuts I have tried un-clicking and re-clicking "override" two times in a row.
* In Settings -> Settings Manager -> Settings Editor -> xfce4-keyboard-
I will report back as to whether these fixes work or not. Obviously this should be fixed in the code though.