Gimp is also, for now, limited to srgb, so anything coming from gimp will work fine with cairo.
And, for a postscript printer, jpegs should be converted directly to ps, not via pdf, so that wouldn't matter either.
But if you used a workflow which used, say, AdobeRGB as the colour working space, and published to pdf, then you would want to avoid cairo.
Or if you used a workflow which ends up with a CMYK pdf.
But if everything you do is in sRGB or grayscale, then pdftocairo is fine for you.
Gimp is also, for now, limited to srgb, so anything coming from gimp will work fine with cairo.
And, for a postscript printer, jpegs should be converted directly to ps, not via pdf, so that wouldn't matter either.
But if you used a workflow which used, say, AdobeRGB as the colour working space, and published to pdf, then you would want to avoid cairo.
Or if you used a workflow which ends up with a CMYK pdf.
But if everything you do is in sRGB or grayscale, then pdftocairo is fine for you.