Comment 3 for bug 686782

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Mathieu Trudel-Lapierre (cyphermox) wrote :

This is a known issue, it's not currently possible to connect to a PPPoE connection over wireless.

There are workarounds though: you can use wired to connect, say, for a first connection, than install and use pppoeconf, pon and poff to control PPPoE connections manually. See https://help.ubuntu.com/community/ADSLPPPoE for all the details on how to do this.