Comment 2 for bug 743681

Starting pinta at commandline:
 $ rm -fr ~/.config/Pinta
 $ pinta
Marshaling activate signal

And doing the procedure as in the first post, I get the exception:

System.Reflection.TargetInvocationException: Exception has been thrown by the target of an invocation. ---> System.IO.DirectoryNotFoundException: Could not find a part of the path "/home/ppareit/.config/Pinta/settings.xml".
  at System.IO.FileStream..ctor (System.String path, FileMode mode, FileAccess access, FileShare share, Int32 bufferSize, Boolean anonymous, FileOptions options) [0x00000] in <filename unknown>:0
  at System.IO.FileStream..ctor (System.String path, FileMode mode, FileAccess access, FileShare share) [0x00000] in <filename unknown>:0
  at (wrapper remoting-invoke-with-check) System.IO.FileStream:.ctor (string,System.IO.FileMode,System.IO.FileAccess,System.IO.FileShare)
  at System.Xml.XmlTextWriter..ctor (System.String filename, System.Text.Encoding encoding) [0x00000] in <filename unknown>:0
  at Pinta.Core.SettingsManager.Serialize (System.String filename, System.Collections.Generic.Dictionary`2 settings) [0x00000] in <filename unknown>:0
  at Pinta.Core.SettingsManager.SaveSettings () [0x00000] in <filename unknown>:0
  at Pinta.DialogHandlers.HandlePintaCoreActionsFileNewScreenshotActivated (System.Object sender, System.EventArgs e) [0x00000] in <filename unknown>:0
  at (wrapper managed-to-native) System.Reflection.MonoMethod:InternalInvoke (object,object[],System.Exception&)
  at System.Reflection.MonoMethod.Invoke (System.Object obj, BindingFlags invokeAttr, System.Reflection.Binder binder, System.Object[] parameters, System.Globalization.CultureInfo culture) [0x00000] in <filename unknown>:0
  --- End of inner exception stack trace ---
  at System.Reflection.MonoMethod.Invoke (System.Object obj, BindingFlags invokeAttr, System.Reflection.Binder binder, System.Object[] parameters, System.Globalization.CultureInfo culture) [0x00000] in <filename unknown>:0
  at System.Reflection.MethodBase.Invoke (System.Object obj, System.Object[] parameters) [0x00000] in <filename unknown>:0
  at System.Delegate.DynamicInvokeImpl (System.Object[] args) [0x00000] in <filename unknown>:0
  at System.MulticastDelegate.DynamicInvokeImpl (System.Object[] args) [0x00000] in <filename unknown>:0
  at System.Delegate.DynamicInvoke (System.Object[] args) [0x00000] in <filename unknown>:0
  at GLib.Signal.ClosureInvokedCB (System.Object o, GLib.ClosureInvokedArgs args) [0x00000] in <filename unknown>:0
  at GLib.SignalClosure.Invoke (GLib.ClosureInvokedArgs args) [0x00000] in <filename unknown>:0
  at GLib.SignalClosure.MarshalCallback (IntPtr raw_closure, IntPtr return_val, UInt32 n_param_vals, IntPtr param_values, IntPtr invocation_hint, IntPtr marshal_data) [0x00000] in <filename unknown>:0

See also in attachment.