Comment 3 for bug 388723

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Robert Collins (lifeless) wrote : Re: [Bug 388723] Re: SSL error on starttls()

tls/ssl isn't about authentication, its about encryption. FWIW.

The only theory I have about what is happening here is that your mail
server is broken - its offering TLS but then erroring, perhaps because
it doesn't have an ssl certificate.

Is it MS Exchange, by chance?

-Rob