Some of the issues I've raised in IRC previously include:
* GNOME Do being written as "Gnome-Do",
* multiple select not working by default because the key binding is not supposed to be "Comma"; it should be "comma" (actually that field name should probably be changed to "multiple select", the current name of "selection mode" seems a little vague).
* not being able to set a shortcut to use the "tab" or "ISO_Left_Tab" keys. For example, if I accidentally set the "Next Pane" shortcut to anything other than "Tab", I can't change it back. Double clicking on a shortcut to assign a new one, then pressing either <tab> or <shift-tab> results in no action and no change of the shortcut.
* The whole layout just seems cluttered. Currently a whole column is shown for default shortcuts, but there's no way at all to actually reset the shortcuts to the default. Why even show the default shortcut? A button or something that would reset it back to the default would make more sense.
I'm marking as a blocker for 0.8.2, but this could do with some thrashing out. It looks like the keybinding preferences need a bit of a rethink.